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Hydrogen peroxide – production, fate and role in redox signaling of tumor cells | Cell Communication and Signaling | Springer Nature Link

doi: 10.1074/jbc.M206835200, 54 GeD.NoakesP

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Note that free radicals residing outside the bilayer are highly unlikely to be involved in mechanisms of lipid peroxidation, since they generally are so reactive that they would immediately react with a nearby substrate and not be able to live long enough to penetrate the lipid bilayer and diffuse to within a van der Waals distance of labile allylic H-atoms on the acyl chains of the phospholipids